The diameter (R K) of the middle semicircle corresponds to SP600125 the resistance associated with the transport of electrons through the dye/TiO2 NP photoanode/electrolyte interfaces The R K values for samples A to F are listed in Table 1. The result indicates that sample D has the smallest R K among the six samples. Figure 4 Nyquist plots of the DSSCs composed of the compressed TiO 2 NP thin film as photoanode. Samples A to F have a photoanode thickness of 12.7, 14.2, 25.0, 26.6, 35.3, and 55.2 μm, respectively, with dye adsorption. Table 1 Characteristics of DSSCs composed of the compressed TiO 2 NP thin film

as photoanode Sample Thickness R K V OC J SC FF η   (μm) (Ω) (V) (mA/cm2) (%) (%) A 12.7 19.2 0.71 12.62 60.89 5.43 B 14.2 12.5 0.68 19.88 57.90 7.80 C 25.0 10.6 0.68 21.59 58.33 8.59 D 26.6 9.41 0.68 22.41 59.66 9.01 E 35.3 9.87 0.66 22.32 56.10 8.30 F 55.2 10.1 GW-572016 clinical trial 0.62 19.37 54.67 5.85 Figure 5 shows the IPCE as a function of wavelength. High IPCE represents high optical absorption and hence improves the incident photon-to-electron conversion efficiency. The IPCE results indicate that the wavelength of incident light that contributes to photo-to-current conversion mainly ranges from 300 to 800 nm. This is because the N3 dye has the highest quantum efficiency at the wavelength

of 540 nm. Thus, for all the samples, the highest IPCE is observed at 540 nm. Sample D has a quantum efficiency of about 67%, which is approximately 12% higher than that of sample

A. Figure www.selleck.co.jp/products/Neratinib(HKI-272).html 5 IPCE characteristics of the DSSCs composed of the compressed TiO 2 NP thin film as photoanode. Samples A to F have a photoanode thickness of 12.7, 14.2, 25.0, 26.6, 35.3, and 55.2 μm, respectively, with dye adsorption. Figure 6 shows the photocurrent density-voltage characteristics of the DCCSs of samples A to F under AM 1.5G. The photovoltaic properties of DSSCs are summarized in Table 1. The open-circuit voltage (V OC) decreases monotonically as the thickness of TiO2 photoanode increases. The result indicates that the recombination rate increases with the increase of photoanode thickness. It is due to the long diffusion distance for the photoelectron to transport to the electrode enhancing the probability of recombination. The short-circuit current density (J SC), however, does not show simple relations with the thickness, in which sample D has the highest density of 22.41 mA/cm2. Figure 6 J – V characteristics of the DSSCs composed of the compressed TiO 2 NP thin film as photoanode. Under AM 1.5G sunlight. The inset shows (a) open-circuit voltage (V OC), (b) overall selleck photo-to-electron conversion efficiency (η), and (c) short-circuit current density (J SC) as a function of photoanode thickness.